Origin of sulphate in the unsaturated zone and groundwater of a loess aquifer     

Yin Long  Tianming Huang  Fen Zhang  Zhenbin Li  Baoqiang Ma  Yiman Li  Zhonghe Pang 《水文研究》2021,35(4):e14166

The use of the sulphate mass balance (SMB) between precipitation and soil water as a supplementary method to estimate the diffuse recharge rate assumes that the sulphate in soil water originated entirely from atmospheric deposition; however, the origin of sulphate in soil and groundwater is often unclear, especially in loess aquifers. This study analysed the sulphur (δ³⁴S-SO₄) and oxygen (δ¹⁸O-SO₄) isotopes of sulphate in precipitation, water-extractable soil water, and shallow groundwater samples and used these data along with hydrochemical data to determine the sources of sulphate in the thick unsaturated zone and groundwater of a loess aquifer. The results suggest that sulphate in groundwater mainly originated from old precipitation. When precipitation percolates through the unsaturated zone to recharge groundwater, sulphates were rarely dissolved due to the formation of CaCO₃ film on the surface of sulphate minerals. The water-extractable sulphate in the deep unsaturated zone (>10 m) was mainly derived from the dissolution of evaporite minerals and there was no oxidation of sulphide minerals during the extraction of soil water by elutriating soil samples with deionized water. The water-extractable concentration of SO₄ was not representative of the actual SO₄ concentration in mobile soil water. Therefore, the recharge rate cannot be estimated by the SMB method using the water-extractable concentration of SO₄ in the loess areas. This study is important for identifying sulphate sources and clarifying the proper method for estimating the recharge rate in loess aquifers.  相似文献   

下辽河平原景观格局演变与预测分析     

吕乐婷  杨勇  姜俊超  乔皓  白少杰 《地理信息世界》2021,28(5):73-78

以下辽河平原为研究对象,选取1980年、2010年和2018年Landsat TM/ETM+OLI卫星图像进行解译,得到3期土地利用数据,定量分析下辽河平原近40年土地利用时空变化特征.结合地形、交通通达度及限制转化因子采用FLUS(Future Land Use Simulation)模型对流域未来土地利用变化情景及景观格局进行了预测.结果表明:1980-2018年水田、林地、草地、沼泽面积均减少,其中水田面积减少量最大,占比减少了8.59％,旱地、水域和城镇的面积均有所上升,旱地的增长面积最大,占比增加了6.19％;水田、林地、水域转入为旱地面积最大,旱地转出为建设用地面积最大;1980-2018年景观格局发生了较大变化,景观的破碎化程度降低,斑块之间的连通度、聚集程度升高,土地利用的集约化程度增大;2018-2040年,下辽河平原建设用地和水田的变化面积最大,城市化过程更加显著,景观的多样性及空间异质性降低,人类对环境的干扰能力变大.  相似文献   

甘肃北山老金厂金矿床载金矿物特征、原位硫同位素组成及其对成矿的指示意义     

黄式庭  于晓飞  吕志成  刘家军  李永胜  杜泽忠  吕鑫  孙海瑞  杜轶伦 《吉林大学学报(地球科学版)》2020,50(5):1387-1403

老金厂金矿床是北山成矿南带最具代表性的中低温岩浆热液型金矿床之一，其规模为中型。依据脉体穿插、矿物共生组合和矿石结构构造等特征，将矿床矿化作用过程划分为石英-黄铁矿阶段（Ⅰ）、石英-含砷黄铁矿-毒砂阶段（Ⅱ）、石英-黄铁矿-多金属硫化物阶段（Ⅲ）和石英-方解石阶段（Ⅳ）。利用电子探针研究了不同成矿阶段载金矿物的元素组成及其分布规律。Ⅰ阶段：黄铁矿以粗粒自形立方体为主，粒度为0.50~1.50 mm，贫As、Au；毒砂含量极少，呈细粒他形。Ⅱ阶段：含砷黄铁矿周围常有大量毒砂产出，含砷黄铁矿多为立方体、五角十二面体，粒度为0.30~1.00 mm，富As、Au；该阶段矿化最为强烈，毒砂主要形成于此时期，多呈棱柱状、柱状、放射状集合体，显示富S亏As特征。Ⅲ阶段：多以黄铁矿-黄铜矿-闪锌矿共生组合脉的形式产出，黄铁矿多呈长条状，以富S、Cu、Zn、Au和贫Fe、As为特征。Ⅳ阶段：矿化作用极弱，毒砂、黄铁矿含量极少，为细粒他形。原位硫同位素组成显示：Ⅰ阶段黄铁矿δ³⁴S_V-CDT值为-3.8‰~-2.9‰，均值为-3.3‰；Ⅱ阶段黄铁矿和毒砂δ³⁴S_V-CDT值为-4.7‰~2.6‰，均值为-3.3‰；Ⅲ阶段黄铁矿和闪锌矿δ³⁴S_V-CDT值主要分布于-1.9‰~1.0‰之间，均值为0.1‰。此3个阶段硫同位素组成反映了成矿期硫主要来源于幔源岩浆，混入了部分地层硫。综合前人研究成果，认为成矿早期至晚期，成矿流体总体上由富S贫As向富As贫S演化。Ⅰ阶段体系处于中性稳定的环境，硫源充足；Ⅱ阶段为贫S富As的高氧逸度环境，由于大气降水对地层的淋滤渗透，混入富As流体，Au可能与As结合形成Au-As络合物，在成矿有利部位富集沉淀；Ⅲ阶段成矿元素种类丰富，体系为富S贫As的弱还原环境，Au很可能与HS^-、S^-形成络合物进入黄铁矿晶格。  相似文献   

Adsorption Mechanism and Kinetic Characterization of Bituminous Coal under High Temperatures and Pressures in the Linxing-Shenfu Area     

TAO Chuanqi  WANG Yanbin  LI Yong  NI Xiaoming  GAO Xiangdong 《《地质学报》英文版》2020,94(2):399-408

The majority of coalbed methane(CBM) in coal reservoirs is in adsorption states in coal matrix pores. To reveal the adsorption behavior of bituminous coal under high-temperature and high-pressure conditions and to discuss the microscopic control mechanism affecting the adsorption characteristics, isothermal adsorption experiments under hightemperature and high-pressure conditions, low-temperature liquid nitrogen adsorption-desorption experiments and CO2 adsorption experiments were performed on coal samples. Results show that the adsorption capacity of coal is comprehensively controlled by the maximum vitrinite reflectance(Ro, max), as well as temperature and pressure conditions. As the vitrinite reflectance increases, the adsorption capacity of coal increases. At low pressures, the pressure has a significant effect on the positive effect of adsorption, but the effect of temperature is relatively weak. As the pressure increases, the effect of temperature on the negative effect of adsorption gradually becomes apparent, and the influence of pressure gradually decreases. Considering pore volumes of pores with diameters of 1.7-100 nm, the peak volume of pores with diameters 10-100 nm is higher than that from pores with diameters 1.7-10 nm, especially for pores with diameters of 40-60 nm, indicating that pores with diameters of 10-100 nm are the main contributors to the pore volume. The pore specific surface area shows multiple peaks, and the peak value appears for pore diameters of 2-3 nm, indicating that this pore diameter is the main contributor to the specific surface area. For pore diameters of 0.489-1.083 nm, the pore size distribution is bimodal, with peak values at 0.56-0.62 nm and 0.82-0.88 nm. The adsorption capability of the coal reservoir depends on the development degree of the supermicroporous specific surface area, because the supermicroporous pores are the main contributors to the specific pore area. Additionally, the adsorption space increases as the adsorption equilibrium pressure increases. Under the same pressure, as the maximum vitrinite reflectance increases, the adsorption space increases. In addition, the cumulative reduction in the surface free energy increases as the maximum vitrinite reflectance increases. Furthermore, as the pressure increases, the surface free energy of each pressure point gradually decreases, indicating that as the pressure increases, it is increasingly difficult to adsorb methane molecules.  相似文献   

天然裂缝影响下的花岗岩水力裂缝扩展数值模拟     

王璜  王贵玲  岳高凡  甘浩男 《地质学报》2020,94(7):2124-2130

水力压裂技术是成功实现干热岩资源开发利用的重要手段之一，数值模拟技术能够精准预测水力裂缝扩展。针对典型花岗岩，借助黏性单元法，分别模拟了致密花岗岩和天然裂缝存在情况下的水力裂缝扩展特征，得出以下结论：致密花岗岩的水力裂缝形态单一，天然裂缝的存在增加了压裂后裂缝的复杂性；致密花岗岩水力裂缝拓展主要分为憋压和拓展两个交替往复的阶段，当存在天然裂隙时，水力压裂过程会变得复杂；天然裂缝存在时，水力裂缝的缝长和缝宽分别为致密花岗岩的5. 7倍和1. 7倍；缝网的形成需要借助复杂的压裂工艺实现。研究结果可以为增强型地热系统(EGS)储层水力刺激工作提供理论支持。  相似文献   

黔北镇远牛蹄塘组黑色页岩沉积环境与有机质富集关系   总被引：1，自引：0，他引：1  

夏鹏  付勇  杨镇  郭川  黄金强  黄明勇 《地质学报》2020,94(3):947-956

通过矿物组分、主量元素、微量元素、碳氧同位素等特征，分析了黔北地区镇远县ZX井牛蹄塘组黑色页岩的岩相类型和不同岩相页岩的沉积环境及其与有机质富集间的关系。结果表明，牛蹄塘组下段以硅质页岩为主，TOC含量4. 96%~10. 10%；上段以富泥硅质页岩为主，TOC含量1. 43%~9. 04%。下段硅质页岩沉积于水流停滞的深水陆棚环境，沉积古水体为贫氧的还原状态；上段富泥硅质页岩沉积时期，仍为贫氧的还原环境，但水体滞留程度、还原性较下段硅质页岩沉积期弱。贫氧的还原环境是影响牛蹄塘组黑色页岩有机质富集的主要因素，热液作用和陆源碎屑对牛蹄塘组黑色页岩有机质富集的影响较小。  相似文献   

金矿立体地球化学探测模型与深部钻探验证   总被引：1，自引：0，他引：1  

王学求  张必敏  于学峰  杨德平  夏勇  谭亲平  刘耀文  张苏坤  田密  刘汉粮  李瑞红  韩志轩  熊玉新  吴慧  张宝云 《地球学报》2020,41(6):869-885

深部资源地球化学探测科学问题的的焦点是元素大深度垂向迁移机理和立体地球化学探测模型的建立。本文以胶东蚀变岩型金矿和贵州水银洞卡林型金矿钻孔岩芯和地表联合取样获得的数据, 建立千米深度立体地球化学探测模型。蚀变岩型金矿立体地球化学模型显示, Au、S和Hg与金矿密切相关, 分布模式既有相似性又有差异性, Au的立体几何分布模式兼具矿化剂元素S和远程指示元素Hg的双重特征, 金异常和矿化剂元素硫与矿体倾斜方向一致, 反映了成矿过程中流体沿控矿构造的轴向运移; 金异常与类气体元素汞在垂向上一致, 而且出现从矿体到地表的连续贯通式异常, 反映了流体沿微裂隙和纳米孔的垂向迁移。卡林型金矿立体地球化学模型显示, Au、As、Sb、Hg、Tl和S在不整合面都显示高含量特征, 与深部层状主矿体分布一致; 在矿体上覆地层中都存在弱异常, 显示了明显的成矿流体沿隐伏微小断裂垂向迁移特点; 所不同的是Sb和Tl元素在不整合面附近显示了最高的元素含量, 而Sb和Hg在近地表均显示了明显高的异常特征。立体几何模型清晰地显示了矿体的展布特征和范围, 而且金及其伴生元素垂向迁移在地表形成清晰异常, 为利用金及伴生元素和矿化剂元素进行深部矿体三维预测提供了重要依据, 对指导深部金矿勘查发挥了重要作用。针对胶东蚀变岩型金矿地表完全被土壤覆盖区的穿透性地球化学微细粒级土壤采样, 金属活动态提取分析圈定的异常, 经深部钻探验证, 胶东焦家成矿带五一村3200 m钻探, 在2428.00~3234.16 m深度发现6层矿化体, 其中高品位矿体位于2854 m深度; 上宫金矿地表基岩出露, 采集断层泥或裂隙岩石样品, 可以清晰探测深部异常, 经2000 m钻探, 在1312 m处发现高品位金铅锌银矿体; 贵州水银洞采集地表细粒级土壤, 能够直接有效地揭示深部金矿体, 经500~1500 m钻探验证, 在300~1500 m深度新增金资源量203 t。  相似文献   

湍流度随高度的变化及其对城市宏观地形的依赖     

李大全  孙武  欧阳睿康  黄盛  高梦媛  李庆祥  黄启明 《热带地理》2019,39(3):365-376

分别构建广州主建成区垂直比例尺为1﹕2 000、1﹕1 000和1﹕500的3个建筑物模型，利用大型边界层风洞，在西北和东南两风向下，基于中性流模拟分析了复杂城市地形下湍流度随高度的变化及其对宏观地形的依赖。结果表明：风廓线指数α与不同高度的湍流度之间的关系密切，利用现有模型，根据4类粗糙度边界层和不同垂直比例尺，可确定相应的湍流度随高度变化模型的主要系数，预测精度高。城市地形下最大湍流度面发育在0~0.2 h之间狭窄的范围内。用湍流度形态指数β来表征湍流度随高度的变化，无论城市屋脊还是平坦地形，随着风程区的延伸，廓线的指数α升高，湍流度形态指数β降低。表明同一高度湍流度值具有由迎风区、丘顶区向背风区增高，沿风程逐渐增大的规律，对地形部位和风程的依赖性强，与来流翻越简单地形时的特征一致。  相似文献   

The Control of the Spatial and Temporal Differential Evolution of Boundary Faults on Faulted Basins     

Yuhu Liu  Chunhui Cao  Ruilei Li  Jianfeng Zhu  Wen Xu  Lan Huang  Ying Luan 《地球科学进展》2020,35(1):79-87

The boundary faults of faulted basins generally have segmental growth characteristics. Quantitative analysis of fault growth processes and combined models is of great significance for basin formation and evolution and hydrocarbon accumulation. Taking the Fulongquan fault depression in the southern part of the Songliao Basin as an example, using the 3D seismic data and using the fault-displacement length analysis method, the segmental growth and evolution process of the boundary fault is systematically studied, and the control effect of the spatial and temporal differential evolution of boundary faults on faulted basins is analyzed. The study shows that the segmental growth control of the boundary fault of Fulongquan fault depression forms a series of semi-mantle shoals; the sedimentary center of the Shahezi-Yingcheng fault is controlled to migrate from south to north; The slanting and thrusting activities control the height of the anticline trap; the transformation of the boundary fault property controls the evolution of the basin's tectonic pattern from the tandem semi-mantle to the faulted anticline.  相似文献   

水资源约束下的河西走廊城市经济脆弱性时空演变及其影响因素     

张戬  陈佳  黄馨  王子侨 《中国沙漠》2019,39(1):203-211

城市经济脆弱性作为当前脆弱性研究中的重要领域，为人-地系统耦合研究提供了新的视角，并为城市可持续健康发展提供有益的决策支持和管理方法。依据城市经济脆弱性内涵，基于暴露度、敏感性、适应能力构建了城市经济脆弱性评价指标体系，运用熵权TOPSIS法评价河西走廊地区及区域内五市的城市经济脆弱性，并采用障碍度模型识别影响区域城市经济脆弱性变化的因素。结果显示：（1）2006—2015年，河西走廊地区城市经济脆弱性呈现出先曲折下降（2006—2011年）再波动上升趋势（2012—2015年）；（2）河西走廊地区的城市经济脆弱性具有明显的空间特征，经历了东西高、中部低到整体较高的演变过程；（3）阻碍河西走廊地区城市经济脆弱性降低的障碍因子由适应能力逐步转变为暴露度。针对河西走廊地区各市主要障碍因子，提出针对性优化措施。  相似文献